Preparation of SBA-15-PAMAM as a Nano Adsorbent for Removal of Acid Red 266 from Aqueous Media: Batch Adsorption and Equilibrium Studies

Maryam Mirzaie, Abosaeed Rashidi, Habib-Allah Tayebi, Mohammad Esmail Yazdanshenas

Abstract


The purpose of the present study was to increase the adsorption capacity of SBA-15 for acidic dyes. Ordered mesoporous silica SBA-15 was successfully synthesized and functionalized by polyamidoamine (PAMAM) dendrimer to develop an efficient anionic dye adsorbent. The prepared materials were characterized by field emission scanning electron microscope (FE-SEM), Fourier transforms infrared spectroscope (FT-IR) and N2 adsorption–desorption analysis. The study was concocted in the Science and Research Branch of Islamic Azad University of Tehran, Iran in 2016. The produced adsorbent (SBA-15-Den) was applied for the removal of Acid Red 266 (AR266) from aqueous media. The effects of various operational parameters including solution pH, adsorbent dosage, contact time, and temperature on removal of AR266 using SBA-15-Den were investigated in batch adsorption mode. Within the optimum conditions, SBA-15-Den exhibited an excellent adsorptive capability of 1111.11 mg/g. Equilibrium data were best described by Langmuir model (R2 > 0.98) completely.

Keywords


Dye removal; SBA-15-Den; Adsorption Isotherm; Langmuir

Full Text:

XML PDF

References


REFRENCES

Gupta V.K., Suhas, 2009. Application of low-cost adsorbents for dye removal – a review. J Environ Man-age. 90, 2313-2342.

Piccin J.S., Vieira M.L.G., Goncalves J., Dotto G.L., Pinto L.A.A., 2009. Adsorption of FD and C Red No. 40 by chitosan: isotherms analysis. J Food Eng. 95, 16-20.

Dotto G.L., Pinto L.A.A., 2011, Adsorption of food dyes onto chitosan: optimization process and kinetic. Carbohydr Polym. 84, 231-238.

Salehi R., Arami M., Mahmoodi N.M., Bahrami H., Khorramfar S., 2010, Novel biocompatible Composite (chitosan–zinc oxide nanoparticle): preparation, charac-terization and dye adsorption properties. Colloids Surf B. 80, 86–93.

Kamble S.P., Mangrulkar P.A., Bansiwal A.K., Rayalu S.S., 2008. Adsorption of phenol and o-chloro phenol on surface altered fly ash based molecular sieves. Chem Eng J. 138, 73–83.

Zhao D., Huo Q., Feng J., Chmelka B.F., Stucky G.D., 1998. Nonionic tri block and star diblock copoly-mer and oligomeric surfactant syntheses of highly or-dered, hydrothermally stable mesoporous silica struc-tures. J Am Chem Soc. 120, 6024–6036.

Khodakov A.Y., Zholobenko V.L., Bechara R., Du-rand D., 2005. Impact of aqueous impregnation on the long-a georderingand mesoporous structure of cobalt containing MCM-41 and SBA-15 materials. Microporous Mesoporous Mater. 79, 29–39.

Zhao D.Y., Feng J.L., Huo Q.S., Melosh N., Fredrickson G.H., Chmelka B.F., Stucky G.D.,1998. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angestrom pores. Science. 279, 548–552.

Zhao D.Y., Huo Q.S., Feng J.L., Chmelka B.F., Stucky G.D.,1998. Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica struc-tures. J Am Chem Soc. 120, 6024–6036.

Tao Z.M., Xie Y.W., Goodisman J., Asefa T., 2010. Isomer-dependent adsorption and release of cis- and trans-platin anticancer drugs by mesoporous silica nanoparticles. Langmuir. 26, 8914–8924.

Du G., Lim S.S., Pinault M., Wang C., Fang F., Pfefferle L., Haller G.L., 2008. Synthesis, characteriza-tion and catalytic performance of highly dispersed va-nadium grafted SBA-15 catalyst. Catal J. 253, 74–90.

Ikemoto H., Chi Q.J., Ulstrup J., 2010. Stability and catalytic kinetics of horseradish peroxidase confined in nanoporous SBA-15. J Phys Chem C. 114, 16174–16180.

Prieto G., Martinez A., Murciano R., Arribas M.A., 2009. Cobalt supported on morphologically tailored SBA-15 mesostructures: the impact of pore lenghth on metal dispersion and catalytic activity in fischer-tropsch synthesis. Appl Catal A. 367, 146–156.

Badiei A., Goldooz H., Ziarani G.M., Abbasi A., 2011. One pot Synthesis of Functionalized SBA-15 by using an 8-Hydroxyquinoline-5-sulfonamide-modified Organo silane as Precursor. J Colloid Interface Sci. 357, 63- 69.

Bosman A.W., Janssen H.M., Meijer E.W., 1999. About dendimers: structure, physical properties, and applications. Chem Rev. 99, 1665-1688.

Bao C., Ran Lu M., Zhang T., Zhao Y., 2003. Preparation of Au nanoparticles in the presence of low generational poly (amid amine) dendrimer with surface hydroxyl groups. Mater Chem Phys. 81,160–165.

Weir M., Knecht M., Frenkel A., Crooks R., 2010. Structural analysis of Pd / Au dendrimer encapsulated bimetallic nanoparticles. Langmuir. 26, 1137–1146.

Boettcher S.W., Fan J., Tsung C.K., Shi Q., Stucky G.D., 2007. Harnessing the Sol–Gel Process for the Assembly of Non-Silicate Meso structured Oxide Mate-rials. Acc Chem Res. 40,784-792.

Matos J.R., Mercuri L.P., Kruk M., Jaroniec M., 2001. Toward the synthesis of extra-large pore MCM-41 analogues. Chem Mater. 13, 1726-1731.

Marino G., Bergamini M.F., Teixeira M.F.S., Cavalheiro E.T.G., 2003. Evaluation of carbon paste electrode modified with organofunctionalized amor-phous silica in the cadmium determination in a differen-tial pulse anodic stripping voltammetric procedure. Talanta. 59, 1021-1028.

Weber W.J., Morris J., Sanit C.J., 1963. Eng Div Am Soc Civil Eng. 89, 31- 46.

Badiei A., Goldooz H., Ziarani G.M., 2011. A novel method for preparation of 8-hydroxyquinoline functionalized mesoporous silica: Aluminum complexes and photoluminescence studies. Appl Surface Sci. 257, 4912-4918.

Badiei A., Goldooz H., Ziarani G.M., Abbasi A., 2011. One pot synthesis of functionalized SBA-15 by using an 8-hydroxyquinoline-5-sulfonamide-modified organosilane as precursor. J Colloid Interface Sci. 357, 63–69.

Kim S., Ida J., Guliants V.V., Lin J.Y.S., 2005. J Phys Chem B. 109, 6287–6293.

Tayebi H.A., Dalirandeh Z., Shokuhi Rad A., Mirabi A., Binaeian E., 2016. Synthesis of polyaniline/Fe3O4 magnetic nanoparticles for removal of reactive red 198 from textile waste water: kinetic, isotherm, and thermodynamic studies, Desalin. Water Treat. 7, 1-13.

Kyzas G.Z., Bikiaris D.N., 2008. Lazaridis N.K., Low-swelling chitosan derivatives as bio sorbents for basic dyes. Langmuir. 24, 4791–4799.

Crini G., Gimbert F., Robert C., Martel B., Adam O., Crini N.M., Giorgi F.D., Badot P.M., 2008. The removal of Basic Blue 3 from aqueous solutions by chitosan-based adsorbent: batch studies. J Hazard Mater. 153, 96–106.

Khorramfar S., Mahmoodi N.M., Arami M., Gharanjig K., 2010. Equilibrium and kinetic studies of the cationic dye removal capability of novel bio sorbent Tamarindus indicia from textile wastewater. Color Technol. 126, 261–268.

Alley E.R., Water Quality Control Handbook, 8th ed., McGraw Hill: New York, 2000. pp.125–141.

Szyguła A., Guibal E., Ruiz M., Sastre A.M., 2008. The removal of sulphonated azo-dyes by coagulation with chitosan. Colloids Surf A. 330, 219–226.

Shafiabadi M., Dashti A., Tayebi H.A., 2016. Re-moval of Hg (II) from aqueous solution using polypyrrole/SBA-15 nanocomposite: Experimental and modeling. Syn Met. 212, 154-160.

Tayebi H.A., Yazdanshenas M.E., Rashidi A., Khajavi R., Montazer M., 2015. The isotherms, kinetics and thermodynamics of acid dye on nylon 6 with differ-ent amounts of titania and fiber cross sectional shape. J Eng Fiber Fab. 10, 97-108.

Langergren S., Svenska B.K., 1898. About the

theory of so-called adsorption of soluble substances. Kungliga Svenska Vetenskapsakademiens Handlingar. 24, 1–39.

Mahmoodi N.M., Hayati B., Bahrami H., Arami M., 2011. Dye adsorption and desorption properties of Mentha pulegium in single and binary systems. J Appl Polym Sci. 122, 1489–1499.


Refbacks

  • There are currently no refbacks.